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Valuable rare-earth raw materials extracted from industrial waste stream

Fierce competition over raw materials for new green technologies could become a thing of the past, thanks to a discovery by scientists from the University of Leeds.

Researchers from Leeds' Faculty of Engineering have discovered how to recover significant quantities of rare-earth oxides, present in titanium dioxide minerals. The rare-earth oxides, which are indispensable for the manufacture of wind turbines, energy-efficient lighting, and hybrid and electric cars, are extracted or reclaimed simply and cheaply from the waste materials of another industrial process.

If taken to industrial scale, the new process could eventually shift the balance of power in global supply, breaking China's near monopoly on these scarce but crucial resources. China currently holds 95 per cent of the world's reserves of rare earth metals in a multi-billion dollar global market in which demand is growing steadily.

"These materials are also widely used in the engines of cars and electronics, defence and nuclear industries(1). In fact they cut across so many leading edge technologies, the additional demand for device related applications is set to outstrip supply," said Professor Animesh Jha, who led the research at Leeds.

"There is a serious risk that technologies that can make a major environmental impact could be held back through lack of the necessary raw materials - but hopefully our new process, which is itself much 'greener' than current techniques, could make this less likely."

Despite their name, the fifteen rare earth metals occur more commonly within the Earth's crust than precious metals such as gold and platinum, but their oxides are rarely found in sufficient concentrations to allow for commercial mining and purification. They are, however, found relatively frequently alongside titanium dioxide - a versatile mineral used in everything from cosmetics and medicines to electronics and the aerospace industries, which Professor Jha has been researching for the last eight years.

The Leeds breakthrough came as Professor Jha and his team were fine-tuning a patented industrial process they have developed to extract higher yields of titanium dioxide and refine it to over 99 per cent purity. Not only does the technology eliminate hazardous wastes, cut costs and carbon dioxide emissions, the team also discovered they can extract significant quantities of rare earth metal oxides as co-products of the refining process(2).

"Our recovery rate varies between 60 and 80 per cent, although through better process engineering we will be able to recover more in the future," says Professor Jha. "But already, the recovery of oxides of neodymium (Nd), cerium (Ce) and lanthanum (La), from the waste products - which are most commonly found with titanium dioxide minerals - is an impressive environmental double benefit."

The research has been funded by the Engineering and Physical Sciences Research Council (EPSRC), the former DTI's Sustainable Technology Programme and industrial sponsor, Cristal Global in US (formerly Millennium Inorganic Chemicals) through a PhD studentship for team member Graham Cooke.

Professor Jha is available for interview. Please contact:
Jo Kelly, Campuspr Ltd, tel 0113 258 9880, mob 07980 267756, email jokelly@campuspr.co.uk
or
Guy Dixon, University of Leeds Press Office, tel 0113 343 8299, email g.dixon@leeds.ac.uk


Notes to editors:

(1) Rare earth metals are a group of 15 chemically similar elements, grouped separately in the periodic table, known as lanthanides. Their unique properties - catalytic, chemical, electrical, metallurgical, nuclear, magnetic and optical - have led to their use in an extraordinarily wide range of applications, including: automotive catalysts; flints for lighters; pigments for glass and ceramics; compounds for polishing glass; miniature nuclear batteries; superconductors and miniature magnets.


Rare earth metals are also important in the defence industry, where their application includes: anti-missile defence, aircraft parts, communications systems, electronic countermeasures, jet engines, rockets, missile guidance systems and space-based satellite power.
(source: http://seekingalpha.com/article/103972-rare-earth-metals-not-so-rare-but-valuable)


(2) The amount of rare-earth metal oxides available through Professor Jha's patented process is dependent on the origin of titanium dioxide minerals, and can vary from less than 1% to several per cent.

Animesh Jha is Professor of Professor of Applied Materials Science in the School of Process, Environmental and Materials Engineering (SPEME)
His 28 years of expertise encompasses environmental aspects of materials processing for metals and alloys and minerals. He also specializes in glass science especially for rare-earth containing laser materials.

The School of Process, Environmental and Materials Engineering at the University of Leeds is number 3 in the UK after Cambridge and Oxford (2008 Research Assessment Exercise); an impressive 80% of research activity rated internationally excellent or world leading.

A track record of high quality research delivered by world leading academics in three established centres of excellence: Energy and Resources Research Institute; Institute for Materials Research; Institute of Particle Science and Engineering.

With 100 academic and research staff and over 700 students the School is a major player in the field of chemical, process, energy, mining and materials engineering.

The 2008 Research Assessment Exercise showed the University of Leeds to be the UK's eighth biggest research powerhouse. The University is one of the largest higher education institutions in the UK and a member of the Russell Group of research-intensive universities. The University's vision is to secure a place among the world's top 50 by 2015. www.leeds.ac.uk